Man pages matching name ssl_ctx_set1_verify_cert_store in section 3ssl:

SSL_CTX_set1_verify_cert_store.3ssl.en	debian 10 / libssl-doc
SSL_CTX_set1_verify_cert_store.3ssl.en	debian 11 / libssl-doc
SSL_CTX_set1_verify_cert_store.3ssl.en	debian 12 / libssl-doc